Syntax:
INSERT [LOW_PRIORITY | DELAYED | HIGH_PRIORITY] [IGNORE]
    [INTO] tbl_name [(col_name,...)]
    {VALUES | VALUE} ({expr | DEFAULT},...),(...),...
    [ ON DUPLICATE KEY UPDATE
      col_name=expr
        [, col_name=expr] ... ]

Or:

INSERT [LOW_PRIORITY | DELAYED | HIGH_PRIORITY] [IGNORE]
    [INTO] tbl_name
    SET col_name={expr | DEFAULT}, ...
    [ ON DUPLICATE KEY UPDATE
      col_name=expr
        [, col_name=expr] ... ]

Or:

INSERT [LOW_PRIORITY | HIGH_PRIORITY] [IGNORE]
    [INTO] tbl_name [(col_name,...)]
    SELECT ...
    [ ON DUPLICATE KEY UPDATE
      col_name=expr
        [, col_name=expr] ... ]

INSERT inserts new rows into an existing table. The INSERT ... VALUES
and INSERT ... SET forms of the statement insert rows based on
explicitly specified values. The INSERT ... SELECT form inserts rows
selected from another table or tables. INSERT ... SELECT is discussed
further in [HELP INSERT SELECT].

URL: http://dev.mysql.com/doc/refman/5.1/en/insert.html

